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A new and versatile method to produce grafted layers of poly(γ-methyl L-glutamate) (PMLG) on silicon wafers by the ring-opening polymerization of γ-methyl L-glutamate N-carboxyanhydride (MLG-NCA) is described. Compared with the polymerizations in solution, this approach provides grafted synthetic polypeptide layers very easily and reproducibly

Oriented Thin Film Formation by Surface Graft Polymerization of γ-Methyl l-Glutamate N-Carboxyanhydride in the Melt