English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Zendy Plus

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Zendy Tools

Zendy Open

In this contribution we report on a structural investigation of the two-dimensional (2D) supramolecular organization of three bis-urea substituted thiophene derivatives, containing one, two, or three thiophene units, at the solution/graphite interface with scanning tunneling microscopy (STM). The compounds under investigation form highly ordered physisorbed monolayers. It is found that hydrogen bonding between the urea groups of adjacent molecules controls the spatial arrangement on the graphite surface. Molecular modeling and theoretical calculations demonstrate that the thiophene rings are tilted with respect to the surface and have partially overlapping π-systems. This control of the 2D self-assembly is promising for future studies on the electronic properties of these molecules.

Molecular Organization of Bis-urea Substituted Thiophene Derivatives at the Liquid/Solid Interface Studied by Scanning Tunneling Microscopy