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We investigate sensitization efficiency of near-infrared emission and population saturation of trivalent erbium in erbium-quinolinolato complexes photoexcited into the absorption band of the organic sensitizer. At low-excitation levels, we find high (∼80%) sensitization efficiencies. We observe excited-state populationsaturationatinversionthresholdundersubnanosecondpumpingatthe level of one injected photoexcitation per complex. SECTION Kinetics, Spectroscopy

Population Saturation in Trivalent Erbium Sensitized by Organic Molecular Antennae