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Utilizing the strengths of nitrogen doped graphene quantum dot (N-GQD) as asubstrate, here in, we have shown that one can stabilize the catalytically moreactive planar Au 20 (P-Au 20 ) compared to the thermodynamically more stabletetrahedral structure (T-Au 20 ) on an N-GQD. Clearly, this simple route avoidsthe usage of traditional transition metal oxide substrates which have beensuggested and used for stabilizing the planar structure for a long time.Considering the experimental success in the synthesis of N-GQDs and in thestabilization of Au nanoparticles on N-doped graphene, we expect our proposedmethod to stabilize planar structure will be realized experimentally and willbe useful for industrial level applications.

journal of physical chemistry. c./journal of physical chemistry. c

Nitrogen Doped Graphene Quantum Dots as Possible Substrates to Stabilize  Planar Conformer of Au 20 Over its Tetrahedral Conformer: A Systematic DFT  Study