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We propose a theoretical investigation in this paper to understand thebonding and structural properties of neutral Al4Na4 and anion Al4Na3- clusters.We show that the Al4 species in Al4Na4 and Al4Na3- clusters is a rectangularplanar structure with alternate pi-bonds and hence satisfying the basiccriteria for anti-aromaticity. We prove that the Al4Na4 and Al4Na3- clustersare metallo-anti-aromatic compounds

Metallo-Antiaromatic Al4Na4 and Al4Na3- Compounds: A Theoretical Investigation

Metallo-Antiaromatic Al₄Na₄ and Al₄Na₃^- Compounds: A Theoretical Investigation