English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Zendy Plus

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Zendy Tools

Zendy Open

The stereoselective reduction of hexopyranos-5'-yl radicals in alpha-D-Hex p-(1--&gt;4)-D-Hex p disaccharide models is described. These radicals are generated from a 6-O-yl radical located in the other monosaccharic unit through a 1,8-hydrogen atom transfer. The reaction, which is strongly influenced by steric and stereoelectronic effects, permits in some cases the transformation of alpha-D-Hex p-(1--&gt;4)-D-Hex p into beta-L-Hex p-(1--&gt;4)-D-Hex p disaccharides in a single step with high diastereoselectivity.

the journal of organic chemistry

Intramolecular 1,8-Hydrogen Atom Transfer. Stereoselectivity of the Hexopyranos-5′-yl Radical Reactions in Hex<i>p</i>-(1→4)-Hex<i>p</i>Disaccharide Systems

Intramolecular 1,8-Hydrogen Atom Transfer. Stereoselectivity of the Hexopyranos-5′-yl Radical Reactions in Hexp-(1→4)-HexpDisaccharide Systems