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All four optically pure stereoisomers of the strigol analogue GR24 were prepared via two different routes. In the first approach enantiopure ABC-fragments 4 were used as the chiral source, whereas in the alternative route both antipodes of the latent D-ring 6 were employed. Bioassays revealed significant differences in activity between the four stereoisomers in the stimulation of germination of the parasitic weeds Striga hermonthica and Orobanche crenata. Keywords: Striga; Orobanche; germination, GR24

journal of agricultural and food chemistry

Asymmetric Synthesis of All Stereoisomers of the Strigol Analogue GR24. Dependence of Absolute Configuration on Stimulatory Activity of <i>Striga hermonthica</i> and <i>Orobanche crenata</i> Seed Germination

Asymmetric Synthesis of All Stereoisomers of the Strigol Analogue GR24. Dependence of Absolute Configuration on Stimulatory Activity of Striga hermonthica and Orobanche crenata Seed Germination