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Under suitable conditions, C-alkylpyrogallol[4]arenes (PgCs) arrange into spherical metal-organic nanocapsules (MONCs) upon coordination to appropriate metal ions. Herein we present the synthesis and structural characterization of a novel Fe II /Fe III -seamed MONC, as well as studies related to its electrochemical and magnetic behaviors. Unlike other MONCs that are assembled through 24 metal ions, this nanocapsule comprises 32 Fe ions, uncovering 8 additional coordination sites situated between the constituent PgC subunits. The Fe II ions are likely formed by the reducing ability of DMF used in the synthesis, representing a novel synthetic route toward polynuclear mixed-valence MONCs.

journal of the american chemical society

Site-Specific Metal Chelation Facilitates the Unveiling of Hidden Coordination Sites in an Fe<sup>II</sup>/Fe<sup>III</sup>-Seamed Pyrogallol[4]arene Nanocapsule

Site-Specific Metal Chelation Facilitates the Unveiling of Hidden Coordination Sites in an FeII/FeIII-Seamed Pyrogallol[4]arene Nanocapsule

Site-Specific Metal Chelation Facilitates the Unveiling of Hidden Coordination Sites in an Fe^II/Fe^III-Seamed Pyrogallol[4]arene Nanocapsule