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We report the synthesis of several unique, boron-rich pincer complexes derived from m-carborane. The SeBSe and SBS pincer ligands can be synthesized via two independent synthetic routes and are metalated with Pd(II). These structures represent unique coordinating motifs, each with a Pd-B(2) bond chelated by two thio- or selenoether ligands. This class of structures serves as the first example of boron-metal pincer complexes and possesses several interesting electronic properties imposed by the m-carborane cage.

Carborane-Based Pincers: Synthesis and Structure of SeBSe and SBS Pd(II) Complexes