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A new robust and high-yielding synthesis of the valuable U(III) synthon [U(BH4)3(THF)2] is reported. Reactivity in ligand exchange reactions is found to contrast significantly to that of uranium triiodide. This is exemplified by the synthesis and characterization of azamacrocyclic U(III) complexes, including mononuclear [U(BH4)(L)] and dinuclear [Li(THF)4][{U(BH4)}2(μ-BH4)(L(Me))] and [Na(THF)4][{U(BH4)}2(μ-BH4)(L(A))(THF)2]. The structures of all complexes have been determined by single-crystal X-ray diffraction and display two new U(III)2(BH4)3 motifs.

New Chemistry from an Old Reagent: Mono- and Dinuclear Macrocyclic Uranium(III) Complexes from [U(BH4)3(THF)2]

New Chemistry from an Old Reagent: Mono- and Dinuclear Macrocyclic Uranium(III) Complexes from [U(BH₄)₃(THF)₂]