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Pd-catalyzed ortho-C-H iodination directed by a weakly coordinating amide auxiliary using I2 as the sole oxidant was developed. This reaction is compatible with a wide range of heterocycles including pyridines, imidazoles, oxazoles, thiazoles, isoxazoles, and pyrazoles.

Pd(II)-Catalyzed C–H Iodination Using Molecular I2 as the Sole Oxidant

Pd(II)-Catalyzed C–H Iodination Using Molecular I₂ as the Sole Oxidant