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The incorporation of Ti ions within the framework of aluminophosphate zeotype AlPO-5 and their chemical reactivity is studied by means of CW-EPR, HYSCORE, and UV-vis spectroscopies. Upon reduction, Ti(3+) ions are formed, which exhibit large (31)P hyperfine couplings, providing direct evidence for framework substitution of reducible Ti ions at Al sites.

journal of the american chemical society

Elucidating the Nature and Reactivity of Ti Ions Incorporated in the Framework of AlPO-5 Molecular Sieves. New Evidence from<sup>31</sup>P HYSCORE Spectroscopy

Elucidating the Nature and Reactivity of Ti Ions Incorporated in the Framework of AlPO-5 Molecular Sieves. New Evidence from31P HYSCORE Spectroscopy

Elucidating the Nature and Reactivity of Ti Ions Incorporated in the Framework of AlPO-5 Molecular Sieves. New Evidence from³¹P HYSCORE Spectroscopy