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The mechanism of a recently reported aldehyde alpha-oxyamination reaction has been studied using a combination of kinetic, spectrometric, and spectrophotometric techniques. Most crucially, the use of a validated cyclopropane-based radical-clock substrate has demonstrated that carbon-oxygen bond formation occurs predominantly through an enamine activation manifold. The mechanistic details reported herein indicate that, as has been proposed for previously studied alcohol oxidations, complexation between TEMPO and a simple metal salt leads to electrophilic ionic reactivity.

Concerning the Mechanism of the FeCl3-Catalyzed α-Oxyamination of Aldehydes: Evidence for a Non-SOMO Activation Pathway

Concerning the Mechanism of the FeCl₃-Catalyzed α-Oxyamination of Aldehydes: Evidence for a Non-SOMO Activation Pathway