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In contrast with most of their congeners, acyclic and cyclic C-amino phosphorus ylides behave as genuine carbene and phosphine transfer agents for transition metal centers. They allow the facile synthesis of a variety of metal complexes that feature heteroditopic ligands, such as 1,6-(phosphine)(aminocarbene) systems with a biphenyl backbone.

Cyclic C-Amino Phosphorus Ylides as a Source of Bidentate Heteroditopic Ligands (Phosphine/Aminocarbene) for Transition Metals