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With an interdoublet transition (a transition between two states belonging to different (Kramer doublets) as a unifying example, we discuss the contribution of individual resonances to the EPR spectrum of high-spin iron via two kinds of graphical methods that correlate resonance magnetic field with orientational angles and transition probabilities: a «density dot plot» and a multidimensional «spherical colored-dot plot». We reexamine two aspects of the spectra of the oxalate complex of diferric transferrin: the role of the 2→3 interdoublet transition, including special line-shape considerations, and whether accurate values of D and E for the oxalate complex can be obtained from the EPR spectra alone

EPR spectroscopy of interdoublet transitions in high-spin iron: applications to transferrin oxalate