English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Zendy Plus

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Zendy Tools

Zendy Open

In this paper the catalytic performances for the low-temperature water-gas shift reaction of Au/TiO2 type A (from World Gold Council), Au/CeO2 (developed at UPV-CSIC), CuO/Al2O3 (from BASF), and CuO/ZnO/ Al2O3 (from REB Research & Consulting) have been compared. The catalysts were characterized by different techniques such as Raman spectroscopy, BET surface area measurements, temperature-programmed reduction, and high-resolution transmission electron microscopy, which gave additional information on the redox properties and textural and morphological structure of the investigated samples. The performances of these catalysts were evaluated in a wide range of operating conditions in a micro packed-bed reactor. It was observed that the presence of reaction products in the feed (CO2 and H2), as well as CO and H2O feed concentrations, have significant effects on the catalytic performances. With a typical reformate feed the Au/CeO2 catalyst reveals the highest CO conversion at the lowest temperature investigated (150 °C). However, while in the long tests performed the CuO/ZnO/Al2O3 catalyst showed a good stability for the entire range of temperatures tested (150-300 °C), the Au/CeO2 sample clearly showed two distinct behaviors: a progressive deactivation at lower temperatures and a good stability at higher ones. The selection of the best catalytic system is therefore clearly dependent upon the range of temperatures used

Comparison of Nanosized Gold-Based and Copper-Based Catalysts for the Low-Temperature Water−Gas Shift Reaction