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1-Alkanol + alkanenitrile or + benzonitrile systems have been investigated by means of the molar excess functions—enthalpies (HmE), isobaric heat capacities (Cp,mE), volumes (VmE), and entropies—and using the Flory model and the concentration–concentration structure factor (SCC(0)) formalism. From the analysis of the experimental data available in the literature, it is concluded that interactions are mainly of dipolar type. In addition, large HmE values contrast with rather low VmE values, indicating the existence of strong structural effects. HmE measurements have been used to evaluate the enthalpy of the hydroxyl–nitrile interactions (ΔHOH–CN). They are stronger in methanol systems and become weaker when the alcohol size increases. In solutions with a given short chain 1-alkanol (up to 1-butanol), the replacement of ethanenitrile by butanenitrile weakens the mentioned interactions. Application of the Flory model shows that orientational effects exist in methanol or 1-nonanol, or 1-decanol + ethanenitril...

Orientational Effects and Random Mixing in 1-Alkanol + Nitrile Mixtures