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Industrial poly(vinyl chloride) (PVC) plastisols are often formulated using phthalate plasticizers due to their cost-effectiveness and high compatibility with PVC. However, there is a current need to replace these additives by plasticizers that (i) present reduced migration/leaching and volatilization profiles, (ii) can optimize production processes while maintaining the performance of the final plasticized materials, and (iii) reduce toxicological risks to consumers and to the environment. The main objective of this work was to evaluate the effects of the partial replacement (15 and 30% (w/w)) of two conventional plasticizers (diisononyl phthalate (DINP) and acetyltri-2-ethylhexyl citrate (CITROFOL AHII)) by two low-volatility ionic liquids of the phosphonium-type (trihexyl(tetradecyl) phosphonium dicyanamide and trihexyl(tetradecyl) phosphonium bis(trifluoromethylsulfonyl)imide) on the rheological and thermomechanical properties of an emulsion-grade PVC which is usually employed in the production of aut...

industrial and engineering chemistry research

Effects of Two Phosphonium-Type Ionic Liquids on the Rheological and Thermomechanical Properties of Emulsion Poly(vinyl chloride)-Based Formulations Plasticized with DINP and CITROFOL