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Calcium magnesium acetate has been assessed as an agent for the reduction of NOx, SO2, and HCl, at the pilot scale, in a down-fired combustor operating at 80 kWth. In addition to this, the chemical and physical processes that occur during heating have been investigated. Benchmarking of calcium magnesium acetate with a suite of five other carboxylic salts (calcium magnesium acetate, calcium propionate, calcium acetate, calcium benzoate, magnesium acetate, and calcium formate) has been performed. NOx reduction involves the volatile organic content of the carboxylic salt being released at temperatures of >1000 °C, where the reaction of CHi radicals with NO under fuel-rich conditions can result in some of the NO forming N2 in a “reburning” process. Thermogravimetry−Fourier transform infrared (TG−FTIR) studies identified the nature of the decomposition products from the low- and high-temperature decompositions. In addition, the rate of weight losses were studied to investigate the influence of the organic deco...

Characterization of a Process for the In-Furnace Reduction of NOx, SO2, and HCl by Carboxylic Salts of Calcium

Characterization of a Process for the In-Furnace Reduction of NO_x, SO₂, and HCl by Carboxylic Salts of Calcium