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Metathesis reactions of the N-thienylidene-l/d-methionine methyl ester ligand (th-metMe) with suitable palladium starting complexes afforded coordination complexes of the type PdX2(th-metMe), PdX(Me)(th-metMe), and [Pd(Me)(th-metMe)(L‘‘)](O3SCF3) (X = Cl, Br, I; and L‘‘ = MeCN, pyridine, picoline, lutidine) which were studied by NMR with respect to the fluxional behavior of the diastereomeric PdNS six-membered ring chelates. The structure of PdCl2(th-metMe) in the solid state (a = 13.318(5) A, b = 11.365(2) A, c = 13.579(5) A, β = 96.66(4)°) showed a square planar coordination complex in which the ligand is chelating via the imine nitrogen (Pd−N = 2.030(7) A) and the methionine sulfur donor atom (Pd−S1 = 2.283(2) A). The square planar geometry is completed by the chlorides (Pd−Cl1 = 2.275(3) A (trans to the imine nitrogen) and Pd−Cl2 2.322(2) A (trans to the sulfur donor)). The dimeric [PdCl(L‘)]2 complex (L‘ = anionic α-methoxycarbonyl, α-(2-thienylmethylidene)amine, α‘‘-(methylthio)ethane) was formed by...

inorganic chemistry

Coordination Dynamics and Reactivity of Palladium(II) Complexes Containing the <i>N</i>-Thienylidene-<scp>l</scp>/<scp>d</scp>-methionine Methyl Ester Ligand

Coordination Dynamics and Reactivity of Palladium(II) Complexes Containing the N-Thienylidene-l/d-methionine Methyl Ester Ligand