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From the tabulation it appears that an ionic radius of approx. 1.6 +- 0.1 A can be assigned to the borohydride ligand when it forms a bidentate bridge to the metal atom and approx. 1.36 +- 0.06 A when it forms a tridentate bridge to the metal atom. The difference in energy between the various possible modes of bonding is small, and the coordination number of the metal ion and the steric hindrance by other ligands appear to determine which mode of attachment will prevail for the borohydride ligand.

Bonding in metal borohydride complexes