English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Zendy Plus

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Zendy Tools

Zendy Open

The carbon 1s, nitrogen 1s, and oxygen 1s binding energies of a wide variety of transition-metal carbonyl and nitrosyl compounds are subjected to correlative analysis. The carbon 1s and oxygen 1s binding energies of the carbonyls are linearly related to the C-O stretching force constants, and the nitrogen 1s and oxygen 1s binding energies of the nitrosyls are linearly related to the N-O stretching force constants. The data indicate that transfer of electron density to the CO and NO groups is accompanied by weakening of the C-O and N-O bonds. From the relative binding energy shifts it is calculated that, in back-bonding to CO groups, more charge is transferred to the carbon atoms than to the oxygen atoms, and, in back-bonding to NO groups, similar amounts of charge are transferred to the nitrogen and oxygen atoms.

Study of charge transfer in back-bonding to carbonyl and nitrosyl groups