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The fluorine ligands of xenon difluoride may be substituted, one at a time, by other electronegative species. Interaction of the difluoride with the appropriate molar quantity of anhydrous acid, below 0°, yields . the monofluorosulfate, FXeOS02F, which is a colorless solid, m.p. 36.6°, the bis-fluorosulfate, Xe(OS02F)2, whichis a pale yellow solid, m.p. 43450, ~he mon8perchlorate, FXeOClOg' which is a colorless solid, m.p. 16.5° and a yellow solid, which decomposes belo-v1 0°, which is probably the bisperchlorate, Xe(OCl0 3 )2 . All of these xenon difluoride derivatives are thermodynamically unstable and dismutate spontaneously above 0°, the ·

Fluorosulfates and perchlorates of xenon(II) and the salt [(FXeO)2S(O)F]+[AsF6]-