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A number of zerovalent palladium and platinum M(NN)(alkene) complexes, containing the rigid bidentate nitrogen ligands bis(arylimino)acenaphthene (Ar-BIAN) and bis(phenylimino)camphane (Ph-BIC) have been synthetized and characterized. Stable complexes were obtained with electron poor alkenes, such as dimethyl fumarate, fumaronitrile, maleic anhydride, and tetracyanoethylene. Complexes bearing asymmetric Ar-BIAN or Ph-BIC ligands occurred as mixtures of isomers. From IR, UV, and 1 H and 13 C NMR spectroscopy and from substitution reactions it was concluded that the back-donation of electron density from the metal to the alkene is the major factor determining the stability of the complexes

inorganic chemistry

Rigid Bidentate Nitrogen Ligands in Organometallic Chemistry and Homogeneous Catalysis. 6. Zerovalent Palladium and Platinum Complexes Containing Rigid Bidentate Nitrogen Ligands and Alkenes: Synthesis, Characterization, Alkene Rotation and Substitution Reactions. X-ray Crystal Structure of [Bis((2,6-diisopropylphenyl)imino)acenaphthene](maleic anhydride)palladium(0)