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2.7.2. Models Containing Oxygenated Sulfurs 834 2.8. Reactivity Models 835 2.8.1. Models That Bind Inhibitors 836 2.8.2. Models That Bind Hydroxide 837 2.8.3. Models That Bind Nitriles 838 2.8.4. Models That Hydrolyze Nitriles 838 2.8.5. Making Low-Spin Co(III) More Reactive 840 3. Superoxide Reductase (SOR) 840 3.1. Enzyme Function 840 3.2. Active Site Structure and Mechanism 840 3.3. Exogenous Ligand Binding 842 3.4. Biomimetic Models of SOR 843 4. Perspective 845 5. References 846

Synthetic Analogues of Cysteinate-Ligated Non-Heme Iron and Non-Corrinoid Cobalt Enzymes