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The construction of a library of benzothiaoxazepine-1,1'-dioxides utilizing a one-pot, S(N)Ar diversification-ODCT(50) scavenging protocol is reported. This protocol combines microwave irradiation to facilitate the reaction, in conjunction with a soluble ROMP-derived scavenger (ODCT) to afford the desired products in good overall purity. Utilizing this protocol, a 78-member library was successfully synthesized and submitted for biological evaluation.

SNAr-Based, Facile Synthesis of a Library of Benzothiaoxazepine-1,1′-dioxides

S_NAr-Based, Facile Synthesis of a Library of Benzothiaoxazepine-1,1′-dioxides