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During the detection of industrial toxic gases, such as triethylamine (TEA), poor selectivity and negative humidity impact are still challenging issues. A frequently reported strategy is to employ molecular sieves or metal−organic framework (MOF) membranes so that interference derived from surrounding gases or water vapor can be blocked. Nevertheless, the decline in the response signal was also observed after coating these membranes. Herein, an alternative strategy that is based on a hydrophobic, TEA adsorption-selective p−n conjunction core−shell heterostructure is proposed and is speculated to simultaneously enhance selectivity, sensitivity, and humidity resistance. To verify the practicability of the proposed strategy, a thickness-tunable nitrogen-doped carbon (N−C) shell-coated α-Fe2O3 nano-olive (N−C@α-Fe2O3 NO)-based core−shell heterostructure that is obtained via a unique all-vapor-phase processing method is selected as the research example. After forming the core−shell heterostructure, a relatively hydrophobic and TEA adsorption-selective N−C@α-Fe2O3 NO surface was experimentally confirmed. Particularly, a chemiresistive sensor that comprises N−C@α-Fe2O3 NOs exhibits satisfactory selectivity and response magnitude to TEA when compared with the sensor using α-Fe2O3 NOs. The detection limit can even reduce to be 400 ppb at 250 °C. Furthermore, the sensor based on N−C@α-Fe2O3 NOs shows desirable humidity resistance within the relative humidity (RH) range of 30−90%. For practical usage, a sensing prototype based on the N−C@α-Fe2O3 NO probe is fabricated, and its satisfactory sensing performance further confirms the potential for future applications in industrial organic amine detection. These promising results show a bright future in enhancing the humidity resistance and selectivity as well as sensitivity of chemiresistive sensors by simply designing a hydrophobic and target gas adsorption (e.g., TEA) preferred p−n junction core−shell heterostructure.

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From a Relatively Hydrophobic and Triethylamine (TEA)\nAdsorption-Selective Core–Shell Heterostructure to a Humidity-Resistant\nand TEA Highly Selective Sensing Prototype: An Alternative Approach\nto Improve the Sensing Characteristics of TEA Sensors