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Sensitizing titania with semiconducting quantum dots (QDs) is an important field for the development of third-generation photovoltaics. Many methods have been developed to effectively incorporate QDs over the surface of mesoporous titania, assembled from the 20-25 nm titania nanoparticles. Here, we introduce a molten-salt-assisted self-assembly (MASA) method to fabricate CdSe-modified mesoporous titania photoanodes. A mixture of ethanol, two surfactants (cetyltrimethylammonium bromide and 10-lauryl ether), silica (tetramethyl orthosilicate) or titania source (Ti(OC 4 H 9 ) 4 , acid (HNO 3 ), and cadmium nitrate solution was infiltrated into the pores of mesoporous titania (assembled using Degussa 25, P25) and immediately calcined at 450 °C to obtain mesoporous cadmium oxide-silica-titania (meso-CdO-SiO 2 -P25) or cadmium titanate-titania (meso-CdTiO 3 -P25) films. The MASA process is a simple method to smoothly coat or fill the pores of titania with mesoporous CdO-SiO 2 or CdTiO 3 that can be reacted under an H 2 Se atmosphere to convert cadmium species to CdSe at 100 °C. Etching of the silica films with a very dilute hydrogen fluoride solution produces mesoporous CdSe-titania (meso-CdSe-P25) electrodes. The method is flexible to adjust the CdSe/TiO 2 mole ratio over a very broad range in the films. The films were characterized at every stage of the preparation to demonstrate the effectiveness of the method. The electrodes were also tested in a simple two-electrode solar cell to demonstrate the performance of the electrodes that have a power conversion efficiency of 3.35%.

Modifying Titania Using the Molten-Salt-Assisted Self-Assembly Process for Cadmium Selenide–Quantum Dot-Sensitized Photoanodes