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A Sodium Chloride Modification of SnO2 Electron Transport Layers to Enhance the Performance of Perovskite Solar Cells
Author(s) -
Ching Chang Lin,
Takurou N. Murakami,
Masayuki Chikamatsu,
Takeru Bessho,
Miwako Furue,
Hiroshi Segawa
Publication year - 2021
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.1c01286
Subject(s) - tin oxide , passivation , perovskite (structure) , sodium , tin , materials science , oxide , inorganic chemistry , chloride , chemical engineering , layer (electronics) , chemistry , nanotechnology , metallurgy , engineering
A sodium chloride modification was applied where different amounts of sodium chloride was physically blended in a tin oxide colloid solution to passivate the interface between the electron transport layer (ETL) and perovskite layer and improve the performance of perovskite solar cells. Sodium chloride-modified tin oxide was utilized as the electron transport material to fabricate perovskite solar cells. It was found that sodium chloride-modified tin oxide as an ETL could considerably enhance the performance of the device compared to pristine tin oxide. The power conversion efficiency of the perovskite solar cell displayed 8.8% remarkable improvement from 18.7 ± 0.4% to 20.3 ± 0.3% on average and 9.5% improvement from 18.9 to 20.7% in champion devices because of the considerable enhancement of the fill factor when 25 mM sodium chloride-modified tin oxide as the ETL was used in comparison with pristine tin oxide.

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