English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Zendy Plus

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Zendy Tools

Zendy Open

To bring hybrid lead halide perovskite solar cells toward the Shockley-Queisser limit requires lowering the band gap while simultaneously increasing the open-circuit voltage. This, to some extent divergent objective, may demand the use of large cations to obtain a perovskite with larger lattice parameter together with a large crystal size to minimize interface nonradiative recombination. When applying the two-step method for a better crystal control, it is rather challenging to fabricate perovskites with FA + cations, given the small penetration depth of such large ions into a compact PbI 2 film. In here, to successfully incorporate such large cations, we used a high-concentration solution of the organic precursor containing small Cl - anions achieving, via a solvent annealing-controlled dissolution-recrystallization, larger than 1 μm perovskite crystals in a solar cell. This solar cell, with a largely increased fluorescence quantum yield, exhibited an open-circuit voltage equivalent to 93% of the corresponding radiative limit one. This, together with the low band gap achieved (1.53 eV), makes the fabricated perovskite cell one of the closest to the Shockley-Queisser optimum.

Formamidinium Incorporation into Compact Lead Iodide for Low Band Gap Perovskite Solar Cells with Open-Circuit Voltage Approaching the Radiative Limit