English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Zendy Plus

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Zendy Tools

Zendy Open

Bismuth-based oxides exhibit outstanding oxygen ionic conductivity and fast oxygen surface kinetics and have shown great potential as a highly active component for electrode materials in solid oxide fuel cells (SOFCs). Herein, a Nb-doped La 0.6 Sr 0.4 Co 0.2 Fe 0.7 Nb 0.1 O 3-δ (LSCFNb) electrode with 40% Er 0.4 Bi 1.6 O 3 (ESB) composite electrode was successfully fabricated by decoration method and directly assembled on barrier-layer-free yttrium-stabilized zirconia (YSZ) electrolyte cells, achieving a peak power density of 1.32 W cm -2 and excellent stability at 750 °C and 250 mA cm -2 for 100 h. ESB decoration also significantly reduces the activation energy from 214 kJ mol -1 for the O 2 reduction on pristine LSCFNb electrode to 98 kJ mol -1 . Further microstructural analysis reveals that there is a redistribution and migration of the ESB phase in the ESB-LSCFNb composite toward the YSZ electrolyte under the influence of cathodic polarization, forming a thin ESB layer at the cathode/YSZ electrolyte interface. The in situ formed ESB layer not only prevents the direct contact and subsequent reaction between segregated SrO and YSZ electrolytes, but also remarkably promotes the oxygen migration/diffusion at the interface for O 2 reduction reaction, resulting in a remarkable increase in power output and a decrease in activation energy. The present study clearly demonstrated the in situ formation of a highly functional and active ESB protective layer at LSCFNb cobaltite cathode and YSZ electrolyte interface via ESB-decorated LSCFNb composite cathode under SOFC operation conditions.

acs applied materials and interfaces

In Situ Formation of Er0.4Bi1.6O3 Protective Layer at Cobaltite Cathode/Y2O3–ZrO2 Electrolyte Interface under Solid Oxide Fuel Cell Operation Conditions