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To understand the behavior of corrosion films on X65 C-steel under CO2conditions is paramount to identify the formation and transformations ofcorrosion products. This work presents the chemical changes and mechanicaleffects produced by pH and flow on corrosion films through the combination ofmolecular techniques with imaging. Siderite, wustite and magnetite wereidentified as corrosion products at neutral pH, which dissolved and mechanicaldamaged at low pH by a 1m/s brine flow with a crystal size reduction of ~80%.In contrast, at pH 7 and 1m/s flow facilitated the removal of entire crystalsfrom the film.

Mechanistic insights of dissolution and mechanical breakdown of FeCO3 corrosion films