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The greater geometric lability of hydrazones compared to that of oxime ethers is used as a basis to overcome the reluctance of Z -oxime ether azatrienes to undergo electrocyclization toward the synthesis of borylated (heteroaromatic) pyridines and ring-fused analogues. Such hydrazones now allow access to previously inaccessible tri- and tetrasubstituted 3-borylpyridines in high yields.

Exploiting Hydrazones To Improve the Efficiency of 6π-Electrocyclization Reactions of 1-Azatrienes