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The synthesis and application of a newly designed C 2 -symmetric chiral bifunctional triamine family ( C 2 -CBT) is reported. These enantiopure chiral triamine scaffolds can be accessed in multigram amounts from simple amino acids while avoiding chromatographic purification. As a proof of principle, C 2 -CBT has been studied in the aldol reaction of cyclic ketones with isatins, with the target tertiary alcohols being formed in a highly efficient manner. Catalyst recovery by simple extraction techniques and subsequent reuse has been performed.

Development of C2-Symmetric Chiral Bifunctional Triamines: Synthesis and Application in Asymmetric Organocatalysis

Development of C₂-Symmetric Chiral Bifunctional Triamines: Synthesis and Application in Asymmetric Organocatalysis