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Palladium-catalyzed α-arylation reactions of ketones with simultaneous ortho alkylation offer 1,2,3-substituted arenes. The reactions of 1,ω-dihaloalkanes also allow facile construction of medicinally important tetralines and benzocycloheptenes.

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Palladium-Catalyzed Arylation of Ketones and Acetonitrile with <i>Ortho</i> Alkylation of Aryl Rings: De Novo Synthesis of Tetralines and Benzocycloheptenes

Palladium-Catalyzed Arylation of Ketones and Acetonitrile with Ortho Alkylation of Aryl Rings: De Novo Synthesis of Tetralines and Benzocycloheptenes