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A new gold-catalyzed reaction of ynamides with 3-substituted indoles as nucleophiles is reported. The reaction allows for the synthesis of a new class of 2-vinylindole derivatives in good yields via the intermediacy of a cyclopropyl gold-carbenoid species.

Gold-Catalyzed cis-Hydroarylation of Ynamides with Indoles: Regio- and Stereoselective Synthesis of a Class of 2-Vinylindoles