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Ease of separation of petrol-soluble acetonides derived from the triacetonide of methyl glucoheptonate allows scalable syntheses of rare sugars containing the l-gluco or d-gulo structural motif with any oxidation level at the C6 or C1 position of the hexose, usually without chromatography: meso-d-glycero-d-guloheptitol available in two steps is an ideal entry point for the study of the biotechnological production of heptoses.

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Triacetonide of Glucoheptonic Acid in the Scalable Syntheses of <scp>d</scp>-Gulose, 6-Deoxy-<scp>d</scp>-gulose, <scp>l</scp>-Glucose, 6-Deoxy-<scp>l</scp>-glucose, and Related Sugars

Triacetonide of Glucoheptonic Acid in the Scalable Syntheses of d-Gulose, 6-Deoxy-d-gulose, l-Glucose, 6-Deoxy-l-glucose, and Related Sugars