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Entanglement of charge orderings and other electronic orders such assuperconductivity is in the core of challenging physics issues of complexmaterials including high temperature superconductivity. Here, we report on theobservation of a unique nanometer scale honeycomb charge ordering of thecleaved IrTe2 surface, which hosts a superconducting state. IrTe2 was recentlyestablished to exhibit an intriguing cascade of stripe charge orders. Thestripe phases coexist with a hexagonal phase, which is formed locally and fallsinto a superconducting state below 3 K. The atomic and electronic structures ofthe honeycomb and hexagon pattern of this phase are consistent with the chargeorder nature but the superconductivity does not survive on neighboring stripecharge order domains. The present work provides an intriguing physics issue anda new direction of functionalization for two dimensional materials.

Nanoscale Superconducting Honeycomb Charge Order in IrTe2