English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Heterogeneous ice nucleation at the water-sapphire interface is studied using sum-frequency generation spectroscopy. We follow the response of the O-H stretch mode of interfacial water during ice nucleation as a function of time and temperature. The ice and liquid states each exhibit very distinct, largely temperature-independent responses. However, at the moment of freezing, a transient response with a significantly different intensity is observed, with a lifetime between several seconds and several minutes. The presence of this transient signal has previously been attributed to a transient phase of ice. Here, we demonstrate that the transient signal can be explained without invoking a transient ice phase, as the transient signal can simply be accounted for by a linear combination of time-dependent liquid and ice responses.

Ice Nucleation at the Water–Sapphire Interface: Transient Sum-Frequency Response without Evidence for Transient Ice Phase