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The particular ferroelectric domain structure of periodic opposite domain lithium niobate (ODLN) crystals has been used for the first time for structured nanoparticle trapping. The surface charge density produced by a temperature change in this pyroelectric material is the origin of the trapping forces: dielectrophoretic on neutral particles and electrophoretic on charged ones. Metallic and dielectric particles are trapped and structured. The results show that ODLN structures are efficient substrates for pyroelectric trapping. The different trapping behaviors are presentedThis work has been supported by the Spanish Ministerio de Economía y Competitividad under grant ref.: MAT2014-57704-C3-1-

Pyroelectric Trapping and Arrangement of Nanoparticles in Lithium Niobate Opposite Domain Structures