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We systematically evaluated the physicochemical properties of a series of M[FTA]-[C 4 C 1 pyrr][FTA] ionic liquids (ILs) (M = alkali metal, FTA = (fluorosulfonyl)(trifluoromethylsulfonyl)amide, C 4 C 1 pyrr = N -butyl- N -methylpyrrolidinium) as electrolytes for alkali metal-ion batteries. First, the viscosity (η), ionic conductivity (σ), and density (ρ) of the M[FTA]-[C 4 C 1 pyrr][FTA] ILs a x (M[FTA]) = 0.20 ( x (M[FTA]) = molar fraction of M[FTA]) were measured. The σ values ranged from 1-3 mS cm -1 at 298 K and increased as follows: Na &lt; Li &lt; K &lt; Rb &lt; Cs, which indicated that the Li-based IL did not obey the trend predicted by the charge densities of alkali metal cations. Second, the Li-based IL exhibited slightly lower vertical intercept values than the other FTA-based ILs in the Walden plots obtained using the results of η, σ, and ρ measurements. Third, the electrochemical stability of the ILs was investigated by cyclic voltammetry, and the redox potentials of the alkali metals ( E (M + /M)) were determined. The E (M + /M) values of the FTA-based ILs increased as follows: Cs &lt; Rb &lt; K &lt; Li &lt; Na. Subsequently, we compared the obtained E (M + /M) values with those of other general electrolytes, such as propylene carbonate (PC)-based electrolytes and aqueous solutions. The trend in E (M + /M) values of the FTA-based ILs was similar to that of PC-based electrolytes and was significantly different from that of aqueous solutions. In particular, the FTA- and FSA-based ILs (FSA = bis(fluorosulfonyl)amide) presented the most negative E (Na + /Na) and E (K + /K) values among various electrolytes, which indicated that utilization of these IL electrolytes for the development of Na- and K-ion batteries would present significant advantages.

the journal of physical chemistry b

Comparative Study of M[N(SO2F)(SO2CF3)]–[N-Butyl-N-methylpyrroridinium][N(SO2F)(SO2CF3)] (M = Li, Na, K, Rb, Cs) Ionic Liquid Electrolytes