English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Zendy Open

Presents the pdf analysis as premium feature

PDF Analysis

Insights

Presents the summarisation as premium feature

Summarisation

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the zaia usage as premium feature

ZAIA

Zendy Tools

Zendy Plus

Presents the access of premium content as premium feature

Premium Content

In this paper, we experimentally study and model the electron donating character of an axial diamagnetic Pd 2+ ion in four metalloligated lanthanide complexes of formula [PPh 4 ][Ln{Pd(SAc) 4 } 2 ] (SAc - = thioacetate, Ln = Tb, Dy, Ho, and Er). A global model encompassing inelastic neutron scattering, torque magnetometry, and dc magnetometry allows to precisely determine the energy level structure of the complexes. Solid state nuclear magnetic resonance reveals a less donating character of Pd 2+ compared to the previously reported isostructural P 2+ -based complexes. Consequently, all complexes invariably show a lower crystal field strength compared to their P 2+ -analogues. The dynamic properties show an enhanced single molecule magnet behavior due to the suppression of quantum tunneling, in agreement with our model.

Importance of Axial Symmetry in Elucidating Lanthanide–Transition Metal Interactions