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The first bimetallic imidazolates containing alkali and alkaline earth metals, NaMgIm 3 and KMgIm 3 , respectively, are prepared by mechanochemical synthesis and are reported in this paper. NaMgIm 3 has been prepared by the reaction between NaIm and Mg(BH 4 ) 2 as well as directly from NaIm and MgIm 2 . Structural evolution and thermal stability were followed by an in situ high-temperature X-ray powder diffraction experiment utilizing synchrotron radiation. In both compounds, the imidazolate ligand is connected to four metal cations forming a complex three-dimensional network with channels running along the c-direction. NaMgIm 3 and KMgIm 3 are the first members of a new family of imidazolate frameworks with stp topology. The formation of mixed-alkali-metal imidazolate compounds is thermodynamically controlled. LiIm and MgIm 2 have not yielded a mixed-metal compound, while KIm reacts swiftly and forms KMgIm 3 .

inorganic chemistry

Mixed-Metal Imidazolates Containing Alkali and Alkaline Earth Metals: Mechanochemical Synthesis and Crystal Structure of AMgIm<sub>3</sub> (A = Na or K)

Mixed-Metal Imidazolates Containing Alkali and Alkaline Earth Metals: Mechanochemical Synthesis and Crystal Structure of AMgIm3 (A = Na or K)

Mixed-Metal Imidazolates Containing Alkali and Alkaline Earth Metals: Mechanochemical Synthesis and Crystal Structure of AMgIm₃ (A = Na or K)