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We grew large single crystals of the cluster magnet Nb 3 Cl 8 with a magnetic triangular lattice and investigated its magnetic properties and crystal structure. In Nb 3 Cl 8 , the [Nb 3 ] 8+ cluster has a single unpaired spin, making it an S = 1/2 triangular lattice anti-ferromagnet. At low temperatures, Nb 3 Cl 8 exhibits a magnetic-nonmagnetic phase transition driven by a charge disproportionation, in which the paramagnetic [Nb 3 ] 8+ clusters transform into alternating layers of nonmagnetic [Nb 3 ] 7+ and [Nb 3 ] 9+ clusters. The observed exotic phenomenon with the strong correlation between the magnetism and structure are based on the nature of the cluster magnetism.

inorganic chemistry

Magnetic–Nonmagnetic Phase Transition with Interlayer Charge Disproportionation of Nb3 Trimers in the Cluster Compound Nb3Cl8