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The 1:1 mixing of a pair of enantiomers of a cyclic Au(I)4Co(III)2 hexanuclear complex having penicillaminate (pen) and 1,2-bis(diphenylphosphino)ethane (dppe), [Au4Co2(dppe)2(d-pen)4](2+) (d4-[1](2+)) and [Au4Co2(dppe)2(l-pen)4](2+) (l4-[1](2+)), in solution produced an additional stereoisomer, [Au4Co2(dppe)2(d-pen)2(l-pen)2](2+) (d2l2-[1](2+)), because of the scrambling of [Co(d-pen)2](-) and [Co(l-pen)2](-) units between d4-[1](2+) and l4-[1](2+). Upon crystallization with NO3(-), the three stereoisomers were independently crystallized to form three different kinds of crystals, homochiral crystals of d4-[1](NO3)2, homochiral crystals of l4-[1](NO3)2, and heterochiral crystals of d2l2-[1](NO3)2, showing a unique example of the self-recognition and organization of three stereoisomers upon crystallization.

inorganic chemistry

Chiral Scrambling and Independent Crystallization of <scp>d</scp>4, <scp>l</scp>4, and <scp>d</scp>2<scp>l</scp>2 Isomers of an AuI4CoIII2 Hexanuclear Complex with Mixed Penicillaminate and Bis(diphenylphosphino)ethane

Chiral Scrambling and Independent Crystallization of d4, l4, and d2l2 Isomers of an AuI4CoIII2 Hexanuclear Complex with Mixed Penicillaminate and Bis(diphenylphosphino)ethane

Chiral Scrambling and Independent Crystallization of d₄, l₄, and d₂l₂ Isomers of an Au^I₄Co^III₂ Hexanuclear Complex with Mixed Penicillaminate and Bis(diphenylphosphino)ethane