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Nonaqueous magnesium–oxygen (or “Mg-air”) batteries are attractive next generation energy storage devices due to their high theoretical energy densities, projected low cost, and potential for rechargeability. Prior experiments identified magnesium oxide, MgO, and magnesium peroxide, MgO2, as the primary discharge products in a Mg/O2 cell. Charge transport within these nominally insulating compounds is expected to limit battery performance; nevertheless, these transport mechanisms either are incompletely understood (in MgO2) or remain a matter of debate (in MgO). The present study characterizes the equilibrium conductivity associated with intrinsic (point) defects within both compounds using first-principles calculations. For MgO, negative Mg vacancies and hole polarons—the latter localized on oxygen anions—were identified as the dominant charge carriers. However, the large formation energies associated with these carriers suggest low equilibrium concentrations. A large asymmetry in the carrier mobility is...

Intrinsic Conductivity in Magnesium–Oxygen Battery Discharge Products: MgO and MgO2

Intrinsic Conductivity in Magnesium–Oxygen Battery Discharge Products: MgO and MgO₂