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Five new cocrystals of 2,6-dimethylpyridine (DMP) with formic acid (FA) were crystallized by application of pressure in a diamond anvil cell and by in situ cryo-crystallization. Mixtures in ratios 1:1, 1:2, and 1:3 of DMP–FA have crystallized via both methods. Both the 1:2 and 1:3 cocrystals exhibit high pressure/low temperature polymorphism

High Pressure/Low Temperature Polymorphism in 2,6-Dimethylpyridine–Formic Acid Cocrystals