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Polycrystalline Ba4NbIr3O12 has recently been shown to be a promising spinliquid candidate. We report an easy and reliable method to growmillimeter-sized single crystals of this trimer based spin liquid candidatematerial with the actual stoichiometry of Ba4Nb0.8Ir3.2O12. The growth of largecrystals is achieved using BaCl2 as flux. The crystals show hexagonalplate-like habit with edges up to 3 mm in length. The structure is confirmed bysingle crystal X-ray diffraction and is found to be the same as of previouslyreported phase Ba12Nb2.4Ir9.6O36 [Ba4Nb0.8Ir3.2O12], indeed with a mixedoccupancy of Nb/Ir at 3a site. The magnetic and calorimetric study on theindividual single crystals confirms the possibility of a spin liquid stateconsistent with a recent report on a polycrystalline sample

Crystal Growth of Spin-Frustrated Ba4Nb0.8Ir3.2O12: A Possible Spin Liquid Material