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In the framework of presented studies, various metallocomplexes (mainly metalloporphyrins) have been tested in plasticized aminated or carboxylated poly(vinyl chloride) (PVC) and unplasticized polyurethane instead of usually used plasticized PVC-based membranes. Such modification allows for relatively simple preparation of miniaturized planar electrodes (thanks to good adhesion of these membranes to certain substrates) or immobilization of biomolecules to prepare biosensors (thanks to functional groups of applied polymers). It was found, that the presence of functional groups of applied polymers can influence the complexing properties of tested ionophores and consequently the working parameters of ion-selective electrodes prepared with their use

Application of Metallocomplexes as Ionophores in Various Polymer Matrices