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In this work we theoretically consider the OPE-3 molecule bridging twometallic leads and show that because of the electron-phonon interaction and thetransition of cation to triplet states, we can have a light induced negativedifferential conductance. Furthermore, we investigate the effects of lightintensity and temperature on this phenomena.

Light Induced Negative Differential Conductance in Molecular Junctions: Role of Triplet States and Electron-Phonon Interaction